Airmed Flight Academy is one of the top schools in Spain.
They train for a JAR/FCL licenced ATPL and have the ISO9002 certificate and are member of the EAAPS organisation (grouping the 10 or so best schools of Europe).
They fly from Valencia International Airport (Manises) and courses are in English.
You might be able to do a PPL also there...
visit them at
www.airmed.es
ps.their equipment includes: C172
P28 and Seneca's.
Sims are: Frasca142 (for procedural training) and A320 full motion sim (for LOFT/MCC/Jet Orientation)