Hi Enemymine,
A330 flies daily to AMS/CDG and a few times a week to FRA via Changsha i think.
Currently no A330 RSP's anywhere other than Australia although from what i heard recently, the idea of a base somewhere in Europe has been touted so maybe something for the future. I think at the moment they are looking to try and open a stable 787 RSP as when Vancouver closes this year that will be 2 opened and 2 closed in a very short period of time. For this reason they seem to be looking into LHR for the 787. I guess they will focus their efforts there first and then on another A330 RSP after perhaps.
All the best,
85