It's an expensive way of doing things, and a more complex aeroplane than you need - so will take a few more hours to get your PPL.
But, if you can afford it and find an amenable school - I can see no reason why not. It's a good capable aeroplane, and if that's what you're going to fly long term, you'll be a much better pilot in it for having learned in the aeroplane.
I like the C182, much nicer handling, roomier, and better performing than the C172.
G