SEE THE STICKY AT THE TOP OF THIS TOPIC.
Send your resume to Flying Schools that have associations with multi-engine commercial/charter ops so you can instruct first, (VFR PPL/CPL) and then work your way up to IFR multi-engine charter ops or whatever else the FBO does...
Get floatplane (seaplane) training if you are planning on living near large bodies of water.
Business administration experience could be quite an asset to get in the door..
Air Hart is one of several FBOs providing bush plane training and float plane training:
www.air-hart.com