With St. Catharines Flying Club you can log the time in your book as dual with an instructor on the tour. You have two airport options to fly out of. You can either do CNQ3 (Welland/Central) or CYSN. Personally, I would do CYSN as it's closer to civilization and you get a better tour. Plus they have an ops spec to fly into the restricted airspace, getting you closer to the falls.