SOPS - I do not quite undertstand your logic? I assume you realise I am referring to ground holding, otherwise the engine flow rate would avoid any over-filling of a wing tank?
Putting centre tank pumps on with lowish contents before take-off WILL give you a large fuel imbalance in the climb due to the location of the 2 centre tank pumps and their different flow rates. Therefore in my experience it is normal to leave these pumps off at certain fuel states until some point in the climb/cruise.