No, skaz, you cannot.
The only licence that the Feds will "give" to you freebie is a "Restricted PPL" - this is just to fly around the United States, in VFR, in N registered aircraft, for fun.
Most of the bits you will want to read about licensing are covered in FARs Part 61,
freebie link to a site that will let you see it.
If you want to buy your own copy,
Amazon will oblige.