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Old 30th Jan 2013, 14:24
  #509 (permalink)  
cwatters
 
Join Date: Dec 2001
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In five of the 10 replacements the main battery had showed an unexpectedly low charge
Would be nice to know what that line actually means because ..

Lithium Battery Failures

Under-voltage / Over-discharge

Rechargeable Lithium cells suffer from under-voltage as well as over-voltage. Allowing the cell voltage to fall below about 2 Volts by over-discharging or storage for extended periods results in progressive breakdown of the electrode materials.

Anodes
First the anode copper current collector is dissolved into the electrolyte. This increases the self discharge rate of the cell however, as the voltage is increased again above 2 volts, the copper ions which are dispersed throughout the electrolyte are precipitated as metallic copper wherever they happen to be, not necessarily back on the current collector foil. This is a dangerous situation which can ultimately cause a short circuit between the electrodes.
But that's an issue at very low voltages. The protection circuits should & did disconnect the batteries before they got that low.

Last edited by cwatters; 30th Jan 2013 at 14:33.
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