LE slats
Although the Concorde site describes them as slats, the LE changes were a simple LE droop as shown in the Concorde 'B' site sketch.
The intention was to give some forward facing area (at low speed) so that the LE suction had something to work on and give "LE thrust". The AoA for vortex generation would have been delayed, but the net effect was to reduce TO drag and hence power required in noise abatement climb. For cruise the LE went back to its normal position of course.
The original prototype had a similar LE droop to the Concorde 'B' (but a bit less extreme). It was changed when it was found that the droop generated an underwing vortex at low AoA (towards zero 'g') at supersonic speeds and that this vortex went down the intake with unpleasant effects on engine face distortion. This could be avoided with the moveable LE.