I fully understand that the more octane (or lead to an extent) a fuel has, the more resistant to pre-det it has. That's pretty common household knowledge.
I guess what I need to understand now is why aero engines need so much spark advance (?)
edit:
I think the fuel is leaded to prevent damage to the valve components in engines of old design, rather than to prevent detonation.
ahhh...forgot about that. Good point!