if scale= 1:1000,000,then 1 inch on chart=1000,000 inches on map.
Since 1 inch equals 2.54 cm, so 1000,000 inches=2540000 cms =25400m=25.4km=25.4/1.852Nms=13.71 Nms
or
since 12 inches=1 feet
1000,000 inches = 1000,000/12=83333.33ft
1 nm = 6080 ft therefore 83333.33/6080=13.7Nms