No mate it can't.
500 hours Multi-Pilot operations on aeroplanes type • certificated in accordance with the JAR/EASA-CS/ FAR-25 Transport Category or the JAR/EASA-CS/ FAR-23 Commuter Category or BCAR or AIR 2051
Aeroplanes not sim. I use to work in PLD at the CAA, had this question a lot, answer is definitely a no.
You must have all the flight experience before the ATPL LST too.
VJW