According to some on here the PIC is not a Captain unless it's a multi crew aeroplane.
So with that logic, the hours don't count and the PIC is a Pilot and not a Captain as it is a single pilot certified aeroplane
.
Go for it, it can't hurt (Unless you factor in the twotter cruise speed
)
P.S Aeroplanes like the Metro/Bandit etc are all in the same boat too!