Hello,
At a glance, what the others here have not picked up on is your question :
Was wondering if there is a way for me to get on my desktop, whilst another user is on theirs?
In technical terms, not only do you want multiple simultaneous usage, but you also want to use multiple profiles simultaneously. None of the solutions mentioned thus far (e.g. "LogMeIn", "VNC" etc.) will let you do that.
Not possible to do what you want under any Microsoft desktop software, irrespective of version. Both due to licensing, but mainly due to commercially imposed technical constraints (i.e. they want you to buy Windows Server)