I recommed you AEREA
Aérea FTO - Centro de Formación Aeronáutica
I did my IFR and my ATPL(H) there and they mean bussines.
If you are interested on IFR jobs that would be a good one to go.
In the other hand if you re more interested on Firefighting, FAASA is a good choice as well.
However as somebody said here, be advise our Civil Aviation Authority is surely not the fastest and easiest in Europe .
Anyway, if you go through an FTO they will take care of all paperwork and procedures so this issue would mean not much difference to you.