For a basic PPL in the circumstances you mention, I think you'll find the relevant restriction is contained in the
ANO Schedule 8, where it says ...
PART A – FLIGHT CREW LICENCESSection 1 – United Kingdom LicencesSub-Section 1 AEROPLANE PILOTSPrivate Pilot’s Licence (Aeroplanes) ...
Privileges:
...
(2) He shall not:
...
(c) unless his licence includes an instrument rating (aeroplane) or an instrument meteorological conditions rating (aeroplanes), fly as pilot in command of such an aeroplane:
...
(iii) out of sight of the surface;
Hope this helps ...
JD