A lot of things that we don't know here and that I would like to know;
Hollywood's got a PPL, but how many hours?
How many in the last year/6 months/30 days?
How many on a complex?
How many on the type that you are looking to rent?
Keep in mind that a lot of places only have one " complex single" and they are not about to give it away to somebody who they don't know.
It's not only matter if you are legal to do so..it's also common sense.
There's lotsa stuff you can do in those 5 hrs if you don't need all of them to get familiar with the airplane;
some advanced maneuvers, instrument work, cross wind landings anything that you can come up with.