Pinguino,
I wouldn't waste your time with Alitalia Group as they are not doing too well and Mr Berlusconi's plan is to privatize the airline in the next few years. This will mean downsizing the fleet. I expect they'll be laying off pilots and won't be hiring for a while.
Give Gandalf Airlines a ring. They have miracolously found someone that has given them a fresh cash injection. They'll be looking for new drivers soon. There are also a number of start-ups like Air Italy with the Saab 2000s, Neos with B737-800s and a few other outfits.
Buona Fortuna!