I'd guess it will be Chambery from Liverpool 3 x weekly over Winter.
Also another daily service from STN to ???, as the STN to CMF arrives back at STN around 11 am. It may be another Winter Sun route such as ACE or LPA.
Also, there are more longhaul to be announced from GLA, likely YYZ possibly another route too.
There should also be some more shorthaul from GLA to be released too for Winter 06.