Managed to do it by drag and dropping the i386 folder in the directory into the XP-CD folder. Probably more luck than judgement but at least I have moved on a notch. Started messing around with the ISO Buster but I suppose I will have to download NERO 6 as I am not getting the images / text that is in the example. Going to work now so more fun and games tomorrow after the night shift.
Don't die laughing but so far it has taken me the best part of 2 days