Not likely. You need a pretty large pressure differential to experience the bends. For every 30 ft a diver descends, he experiences an additional 1 atmosphere of pressure (actually a little less but eh). A diver at 90 feet is therefore experiencing 4 atm, or 58.8 psi.
On the other hand, the difference between sea level and outer space is only 1 atm. Good thing too, or you'd get the bends while driving in the mountains. I haven't done the math, but I imagine the temperature required to create that much pressure would cook the pilot long before he'd be subject to the bends
