Like most things, jump flying is a catch 22 situation. You need to have a serious amount of experience before you can get into it. Most DZ operators will want you to be a skydiver and an experienced pilot. It is challenging stuff. Every take off is a max all up weight take off and the climb needs accuracy. Dropping the skydivers in the right place is also a fine art with odd side winds and atmospheric conditions at altitude. Most jump ships now use GPS but this does not necessarily make things easier. The jumpers want pin point accuracy and good run ins. Also, flying a 206 with five people outside the door is a real hard core flying exercise. The descent is also a challenge both in piston and turbine aircraft. Ideally a DZ operator will want you to have in excess of 500 hours, an IMC rating and be a skydiver. Take advice from the BPA and if you feel you may be close to the minimum qualifications then place an ad in the BPA magazine 'Skydive - the mag'.