Lfc,
In short, no it wouldn't.
If you went for a job, say in management for a retail company, and you said you had an frozen ATPL, it would make no difference. Infact, if they asked/knew what an frozen ATPL is, it may make you less employable since they may think that you have interests elsewhere.
I'm currently on a 1 year work placement through university (I'm doing a sandwich degree), if they knew that I was studying my ATPL theory to become a commercial pilot, they wouldn't have taken me on.
Hope I've answered your question.