To quote my doc at my recent medical: "We all qualify for a free hour on the shrink's couch for wanting to be pilots in the first place!"
If some of the replies on here seem a bit one sided, just remember this - airlines do not just look at pilot applicants in terms of whether or not they can operate the latest wizzbang-doobryflip-glx-mk7 and how many hours they have to back this up; they are also essentially looking at whether the applicant is able to work under pressure in a position of leadership and management. Having run your own business the odds are good that you can outsell quite a few people on this point, so just make sure you build that into your profile when the time comes.
Just go for it and best of luck!