The Devil is in the detail, you might say. Computers are like that. Wink wink, you might get more help if you tell us exactly what version of Outlook (Express ?) is being used, which OS, and what is "server blah blah smtp,port 0"? What is the "second country" and who is providing the access number?
Have a look at this for various links and tips:
http://www.experts-exchange.com/Oper..._20731635.html
And this "how-to":
http://support.microsoft.com/default...b;EN-US;220852